Shonen Villains who are supervillains.
A supervillain is a character designed to counter a superhero, while strictly speaking this means having abilities well beyond normal humans in the modern age the term has also merged with costumed criminal - these characters oppose the ways of costumed heroes (be they super-powered or otherwise) and often super-villains have a massive list of serious crimes, making those who don the guise of a super-villain rather high in terms of heinousness they must achieve to truly stand out amidst what are basically an entire subculture of colorful terrorists.
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Bowser (The Super Mario Bros. Movie) -
Light Yagami -
Darth Vader -
Adam (Hazbin Hotel) -
Dabi -
Rob (The Amazing World of Gumball) -
Cell -
Frieza
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